Occupational exposure assessment to volatile organic compounds (VOC). A case study in a chemical company

Main Article Content

Josué A. Villalobos-Morales
Jose Carlos Mora-Barrantes
José Pablo Sibaja-Brenes
Germán Zárate-Montero
Rosa Alfaro-Solís
Henry Borbón-Alpízar
Alexa Retana-Díaz

Abstract

The present investigation project was developed in a chemical company which develops, manufactures and trade resins for paints and cosmetic products.  The occupational exposure of workers assessment (OEWA) to volatile organic compounds (VOC) was determined by using a methodology named "Chemical risk: systematic for hygienic evaluation", develop by the French National Institute for Security Research (INRS). The assessment analysed general aspects such VOC environmental concentrations and the evaluation of occupational risk factors chemical products handling and their storage conditions. To gather the necessary data, in situ instrumental tools as site inspections, checklists, and surveys, among others were used. The global evaluation chemical risk assessment also included the following: production process analysis, infrastructure conditions inspection and quantification of internal atmospheric pollutants through the gas chromatography technique (GC). Related with the experimental VOC determination, a total of 22 chemical pollutants were quantified (GC Technique). The N-Butyl was the only compound that exceeded the Threshold Limit Value (TLA) recommended by the Spain National Institute for Safety and Health (INSSBT). The N-butyl is related to health effects such skin allergies and asthma. The results gathered from the OEWA to VOC shows high chemical risk level for 4 chemical compounds. These results indicate the need to prevent worker health effects by modification of some labour conditions. As part of the research and to correct and to prevent future chemical risks an action plan was develop, especially focused on the handling, exposure, and use of chemical volatile organic compounds.

Article Details

How to Cite
Villalobos-Morales, J. A., Mora-Barrantes, J. C., Sibaja-Brenes, J. P., Zárate-Montero, G., Alfaro-Solís, R., Borbón-Alpízar, H., & Retana-Díaz, A. (2024). Occupational exposure assessment to volatile organic compounds (VOC). A case study in a chemical company. Tecnología En Marcha Journal, 37(3). https://doi.org/10.18845/tm.v37i3.6837
Section
Artículo científico

References

R. Gonzalo, “Compuestos Orgánicos Volátiles (COVs) en la industria de pinturas y sus disolventes en Perú, análisis de caso y estrategias de gestión ambiental y salud ocupacional”. Tesis de Maestría, Pontificia Universidad Católica del Perú, Perú, 2017.

D. Grosjean, “In situ organic aerosol formation during a smog episode: Estimated production and chemical functionality”. Atmospheric Environment. Part A. General Topics, vol. 26, no 6, pp. 953-963. 1992. https://doi.org/10.1016/0960-1686(92)90027-I

R. Tong, L. Zhang, X. Yang, J. Liu, P. Zhou, and J. Li, “Emission characteristics and probabilistic health risk of volatile organic compounds from solvents in wooden furniture manufacturing”. Journal of Cleaner Production, vol. 208, pp. 1096-1108. 2019. https://doi.org/10.1016/j.jclepro.2018.10.195

C. H. Halios, C. Landeg-Cox, S. D. Lowther, A. Middleton, T. Marczylo, and S. Dimitroulopoulou, “Chemical in European residences – Part I: A review of emissions, concentrations and health effects of volatile organic compounds (VOCs)”. Science of the Total Environment, vol. 839, 156201. 2022. https://doi.org/10.1016/j.scitotenv.2022.156201

Y. Ren, Z. Qu, Y. Du, R. Xu, D. Ma, G. Yang, Y. Shi, X. Fan, A. Tani, P. Guo, Y. Ge, and J. Chang, “Air quality and health effects of biogenic volatile organic compounds emission from urban green spaces and the mitigation strategies”. Environmental Pollution, vol. 230, pp. 849-861. 2017. https://doi.org/10.1016/j.envpol.2017.06.049

Instituto Nacional de Seguridad y Salud en el Trabajo (INSST). Límites de exposición profesional para agentes químicos en España. 2022. Madrid. 2022. Recuperado de https://www.insst.es/el-instituto-al-dia/limites-de-exposicion-profesional-para-agentes-quimicos-2022

J. C. Mora Barrantes, J. P. Sibaja Brenes, W. Umaña Herrera, y R. Zamora Sequeira, “Sistemas de información para la identificación y clasificación de peligros y riesgos de productos químicos”; EUNA: Heredia, Costa Rica, 2015.

M. Feszterová, “Education for future teachers to OHS principles - Safety in Chemical Laboratory”. Procedia – Social and Behavioral Sciences, vol. 191, no 2, pp. 890-895. 2015. https://doi.org/10.1016/j.sbspro.2015.04.698

S. N. H. Husin, A. B. Mohamad, S. R. S. Abdullah, and N. Anuar, “Chemical health risk assessment at the chemical and biochemical engineering laboratory”. Procedia – Social and Behavioral Sciences, vol. 60, pp. 300-307. 2012. https://doi.org/10.1016/j.sbspro.2012.09.383

E. Tjoe-Nij, C. Rochin, N. Berne, A. Sassi, and A. Leplay, “Chemical risk assessment screening tool of a global chemical company”. Safety and Health at Work, vol. 9, no 1, pp. 84-94. 2017. https://doi.org/10.1016/j.shaw.2017.06.012

F. Sicilia-Gutiérrez, “La peligrosidad en laboratorios químicos: Método para su evaluación y clasificación”. Tesis de Maestría, Universidad de Granada, España, 2013

D. Marín-Sánchez, O. M. de Oca-Abella, y Y. González-Díaz, “Evaluación de riesgos químicos en un laboratorio de química analítica por el método Cossh Essential”. Ciencia en su PC, no 13, pp. 91-106. 2017. Recuperado de https://www.redalyc.org/journal/1813/181353026008/

A. Segura-López, y A. R. Mauri-Aucejo, “Comparación de dos métodos de evaluación simplificada del riesgo químico por inhalación en un laboratorio universitario (COSHH Essential y método basado en el INRS)”. Archivos de Prevención de Riesgos Laborales, vol. 19, no 2, pp. 107-109. 2016. https://dx.doi.org/10.12961/aprl.2016.19.02.5

J. L. Saá-Loor, y A. L. León-Villón, “Evaluación de riesgo químico mediante los métodos INRS y COSHH Essentials en empresa minera Produmin S. A. Camilo Ponce Enríquez 2019” Tesis de Maestría, Universidad del Azuay, Ecuador, 2020

F. Golbabaei, F. Dehghani, M. Saatchi, and S. A. Zakerian, “Evaluation of occupational exposure to different levels of mixed organic solvents and cognitive function in the painting unit of an automotive industry”. Health Promotion Perspectives, vol. 8, no 4, pp. 296-302. 2018. 10.15171/hpp.2018.42

Y. Miyake, M. Tokumura, Q. Wang, Z. Wang, and T. Amagai, “Comparison of the volatile organic compound recovery rates of commercial active samplers for evaluation of indoor air quality in work environments”. Air Quality, Atmosphere and Health, vol. 10, no 6, pp. 737-746. 2017. 10.1007/s11869-017-0465-0

P. Monge, C. Wesseling, J. Guardado, I. Lundberg, A. Ahlbom, K. P. Cantor, E. Weiderpass, and T. Partanen, “Parental occupational exposure to pesticides and the risk of childhood leukemia in Costa Rica”. Scandinavian Journal of Work, Environmental and Health, vol. 33, no 4, pp. 293-303. 2007. 10.5271/sjweh.1146

L. Quesada, “Propuesta del sistema de tratamiento de emisiones de compuestos orgánicos volátiles (COV´s), en el plantel de RECOPE ubicado en el Alto de Ochomogo”. Tesis de Licenciatura, Instituto Tecnológico de Costa Rica, Costa Rica, 2013.

J. Rodríguez, “Inventario de compuestos tóxicos peligrosos del aire en el Gran Área Metropolitana para el año 2007”. Tesis de Maestría, Universidad Nacional de Costa Rica, Costa Rica, 2012.

Y. Zhang, D. Wu, X. Yan, K. Ding, and Y. Guan, “Integrated gas chromatography for ultrafast analysis of volatile organic compounds in air”. Talanta, vol. 154, no 1, pp. 548-554. 2016. https://doi.org/10.1016/j.talanta.2016.04.004

S. M. Dutton, M. J. Mendell, W. R. Chan, M. Barrios, M. A. Sidheswaran, D. P. Sullivan, E. A. Eliseeva, and W. J. Fisk, “Evaluation of the indoor air quality minimum ventilation rate procedure for use in California retail buildings”. Indoor Air, vol. 25, no 1, pp. 93-104. 2015. 10.1111/ina.12125

A. T. Fidler, E. L. Baker, and R. E. Letz, “Neurobehavioural effects of occupational exposure to organic solvents among construction painters”. British Journal of Industrial Medicine, vol. 44, no 5, pp. 292-308. 1987.

Y. Elshorbany, I. Barnes, K. H. Becker, J. Kleffmann, and P. Wiesen, “Sources and cycling of tropospheric hydroxyl radical – An overview”. Zeitschrift für Physikalische Chemie, vol. 224, pp. 7 – 8. 2010. https://doi.org/10.1524/zpch.2010.6136

Y. Huang, S. C. Lee, K. F. Ho, S. S. Hang Ho, N. Cao, Y. Cheng, and Y. Gao, “Effect of ammonia on ozone-initiated formation of indoor secondary products with emissions from cleaning products”. Atmospheric Environment, vol. 59, pp. 224-231. 2012. https://doi.org/10.1016/j.atmosenv.2012.04.059

Most read articles by the same author(s)

1 2 > >>