Valorization of Agroindustrial Waste from Tobacco (Nicotina Tabacum L.), Using it in Mixtures with Recycled Cellulosic Pulp, Office and Newspaper Paper for the Preparation of Molded Products
Main Article Content
Abstract
Lignocellulosic biomass refers to organic materials from plants and trees that contain cellulose, hemicellulose and lignin, which are firmly intertwined and chemically bonded in their cell walls. Additionally, these materials may contain other compounds such as extractives and foreign materials. Cellulose, hemicellulose and lignin are also the main components of natural fibers, which come from various resources such as wood, recycled fibers and agricultural biomass waste such as canola, wheat, rice and hemp straw. These fibers are mainly used for the manufacture of molded pulp products. Tobacco cellulose has similar properties to other cellulose sources, such as wood, and can be used to produce paper and other cellulose-based products.
The fibrous material used in this study comes from agroindustrial tobacco waste (Nicotina tabacum L.), which was mixed with recycled cellulose pulp, from office and newspaper paper, for the production of moldable products. To transform the tobacco waste into particles, the hammer mill brand: CONDUX-WERK Wolfgang bei Hanau and model: LHM 20/16 was used. With a motor of: 1.5 Kilowatts / 2.01 HP Mechanical Horsepower, 380 V, 2820 rpm, 0.88 Cos Phi and 50 Hz. The factors selected for the experimental design of this study were the different types of paper used in the mixture: newsprint, office paper and tobacco, and said experimental design was carried out using the Statgraphics simulation software. The preparation and characterization of the raw material (tobacco, Nicotiana tabacum L.) was carried out using the Technical Report NREL/TP-510-42620 standards; where 70 g of each sample were weighed and then processed using the knife mill; These samples were sieved on a set of stacked sieves, where the upper one was 20 mesh and the lower one was 80 mesh. Thus, for the determination of moisture in this biomass, as well as for the determination of structural carbohydrates and lignin in biomass, the standards established in the Technical Report NREL/TP-510-42620 were also used, and for the determination of extractives in biomass, the standards established in the Technical Report NREL/TP-510-42619 were used. To prepare the tobacco fibers, a disc refiner, THE BAUEP BROS brand, was used. CO and model: 148-2, speed 2890 rpm. For the formation of the molds, a molding equipment was used and the corresponding tests were carried out according to the TAPPI T 402 sp-98 standard “Standard conditioning and testing atmospheres for paper, board, pulp handsheets, and related products”. In general, the results indicate that the tobacco (Nicotina tabacum L.) biomass sample has a high content of cellulose and hemicellulose (glucan and xylans), as well as a significant content of lignin; the average cellulose content being 32.61%, while hemicellulose 17.97% and lignin represents 20.71% of the cell wall composition; and a content of 13.58% of extractives and 10.11% of inorganic components.
Article Details

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Los autores conservan los derechos de autor y ceden a la revista el derecho de la primera publicación y pueda editarlo, reproducirlo, distribuirlo, exhibirlo y comunicarlo en el país y en el extranjero mediante medios impresos y electrónicos. Asimismo, asumen el compromiso sobre cualquier litigio o reclamación relacionada con derechos de propiedad intelectual, exonerando de responsabilidad a la Editorial Tecnológica de Costa Rica. Además, se establece que los autores pueden realizar otros acuerdos contractuales independientes y adicionales para la distribución no exclusiva de la versión del artículo publicado en esta revista (p. ej., incluirlo en un repositorio institucional o publicarlo en un libro) siempre que indiquen claramente que el trabajo se publicó por primera vez en esta revista.
References
[1] M. Romano y F. Andrés, “Residuos de la industria de celulosa moldeada. Producción de paneles de relleno para la construcción”. Centro de investigación y desarrollo para la construcción y la vivienda (cecovi) Universidad Tecnológica Nacional – Facultad Regional Santa Fe, 2013
[2] S. Saval, “Aprovechamiento de Residuos Agroindustriales”, Instituto de Ingeniería, UNAM, Ciudad Universitaria,México, D.F, 2012
[3] Rotoplas, “Qué es la agroindustria y por qué es importante en Argentina”, 2021 En línea https://rotoplas.com.ar/agroindustria/que-es-la-agroindustria-y-por-que-es-importante-en-argentina/
[4] A. Sluiter, R. Hames, R. Ruiz, C. Scarlata, J. Sluiter, D. Templeton y D. Crocker, “Determination of Structural. National Renewable Energy Laboratory. Laboratory Analytical Procedure (LAP)”, 2008
[5] M. Cantado, Q. Tarrés, J. Méndez., P. Mutjé y M. Delgado, “Drying kinetics of bleached and unbleached kraft pulps from eucalyptus globulus”. Journal of Applied Polymer Science, 92(1), 332-337, 2004 En línea: https://doi.org/10.1002/app.13563
[6] Y. Liu, C. Cao, H. Guo y D. Luo,“Lignin-derived polyphenol-based carbon dots for imaging-guided chemo-photothermal combination therapy of cáncer”. Journal of Materials Chemistry B, 8(28), 6062-6070, 2020 En línea doi:doi.org/10.1039/D0TB00561D
[7] S. Park, S. Kim, Y. Seo y B. Lee,“Characteristics of cellulose extracted from tobacco stem for pulp and paper production”. BioResources, 15(1), 1218-1232, 2020
[8] T. Lindström, G. Carlsson y P. Larsson,“Pulp and paper chemistry and technology. Fiber Chemistry. Walter de Gruyter”, 2005.
[9] S. Qin, Y. Chen, S.Tao, C. Zhang, X. Qin, P. Chen y H. Qi,“High recycling performance of holocellulose paper made from sisal fibers”. ELSEVIER, 2022.
[10] T. Chakrabarty, N. Karak y B. Sarkar,” Pulp and paper production from tobacco stem: An environment friendly approach for waste utilization”. Journal of Cleaner Production, 117, 1-8, 2016.
[11] Ministerio de Energía y Minas, “Guía de Orientación del Uso Eficiente de la Energía y de Diagnóstico Energético. Lima: dirección general de eficiencia energética ministerio de energía y minas, 2016.
[12] P. Mocchiutti,“Mejora de propiedades papeleras de pulpas celulósicas lignificadas de reciclo. Aplicación de tratamientos oxidativos enzimáticos y químicos”. Instituto de Tecnología Celulósica – Facultad de Ingeniería Química Universidad Nacional del Litoral, 2007.
[13] M. Didone. Y G. Toselló, “Molded pulp products for food packaging: State of the art and research challenges”. Journal of Agricultural Engineering, 50(2), 63-79, 2019.
[14] P. Panneerselvam, K. Mahesh, K. Varadharajan, K. Shanmugarajan, P. Srinivasan y V. Krishnaswamy, “Review of tobacco waste management techniques”. Environmental impact assessment review, 86, 106531, 2021.
[15] P. Peng, L. Chen y H. Chen,“The manufacture of food packaging from bamboo pulp”. Packaging Technology and Science, 19(1), 41-49, 2006. En línea https://doi.org/10.1002/pts.710
[16] P. Rattanawongkun, N. Kerddonfag, N. Tawicha, U. Intatha y N. Soykeabkaew, “Improving agricultural waste pulps via self-blending concept with potential use in moulded pulp packaging”.Journal of Environmental Chemical Engineering, 2020.
[17] F. López, R. Zuluaga, C. Orrego y P. Gañán,“Cellulose chemistry and applications. Nova Science Pub Incorporated”, 2018.
[18] S. Rattanawongkun, N. Ke, P. Tawich, U. Intatha y N. Soykeabkaew,“Evaluation of physical properties of paper sheets made from agricultural residues”. Journal of Material Cycles and Waste Management., 22, 35-45, 2020.
[19] K. Dubey y A. Singh, “Paper production from recycled waste paper by pulping: A review”. Journal of Materials Research and Technology, 13, 18-27, 2021. En línea https://doi.org/10.1016/j.jmrt.2020.10.052
[20] K. Semple, C. Zhou, O. Rojas, W. Nguegang y C. Dai, “Moulded pulp fibers for disposable food packaging: A state-of-the-art review”. Food Packaging and Shelf Life., 33, 2022.
[21] M. Ghorbani, P. Rezayati., A. Raisi, M. Faezipour y M. Taherzadeh, “Agricultural residue pulping and paper production”, Cellulose, 27(18), 10489-10517, 2020. En línea https://doi.org/10.1007/s10570-020-03449-5
[22] E. Miedes, M. Minteguiaga, A. Vallejo y F. Vilaseca, “New strategies to improve physical properties of recycled paper. Environmental Science and Pollution” Research, 26(19), 19779-19791, 2019.
[23] B. Saha y R. Chowdhury, “Hemicellulose Biorefineries. Biochemical and Biophysical”, Research Communications, 534, 616-624, 2021. En línea https://doi.org/10.1016/j.bbrc.2020.11.068
[24] Q. Tarrés, F. Espinach, S. Boufi y P. Mutjé,“The challenge of increasing the use of recycled fibers in papermaking”. The current state of the art. BioResources, 12(1), 2143-.2160, 2017.
[25] P. Zhao, Y. Liu, B. Zhang, Y. Li, F. Wang y L. Chen, “Caustic lignin enhances properties of bagasse pulp through spin coating”. Cellulose, 27, 8825-8834, 2020. En línea https://doi.org/10.1007/s10570-020-03343-0
[26] Y. Zhang, Y. Duan, V. Bokka, K. He y Y. Ni,“Biodegradable and Compostable Thermoplastic Starch-Based Materials for Sustainable Packaging Applications”. Polymers, 13(18), 3120, 2021.
[27] Y. Wang, L. Zhu, C. Li, L. Wang y X., ”A critical review of lignocellulose crystallinity in biomass conversión”. International Journal of Biological Macromolecules, 176, 38-48, 2021.
[28] B. Hames, R. Ruiz, C. Scarlata, A. Sluiter, J, Sluiter y D. Templeton,“Technical Report NREL/TP-510-42620. Preparation of Samples for of Samples for Compositional Analysis. (L. A. (LAP), Ed.)” National Renewable Energy Laboratory, 2008.
[29] H. Zhang, C. Duan, S. Bokka, H. He y Y. Ni, “Life cycle assessment and optimization of paper recycling system considering regional carbon intensity and transport distance in China”. Journal of Cleaner Production, 315, 128162, 2021. En línea https://doi.org/10.1016/j.jclepro.2021.128162
[30] Y. Vargas y L. Peréz, “Aprovechamiento de residuos agroindustriales en el mejoramiento de la calidad del ambiente”. Revista Facultad de Ciencias Básicas, 2018.
[31] X. Tian, H. Liu, X. Teng, R. Yang y X. Li, “Chemical composition and characteristics of cellulose fiber from tobacco stem”. Industrial Crops and Products., 128, 551-557, 2019.
[32] Q. Tarrés, N. Pellicer, A. Balea, N. Merayo, C. Negro, A. Blanco y P. Mutjé, “Lignocellulosic micro/nanofibers from wood sawdust applied to recycled fibers for the production of paper bags”. Elsevier, 2017.
[33] L. Wang y S. Li, “Review on research of pulp molded product quality and production technology”. Advanced Materials Research, 1043, 784-790, 2014. En línea https://doi.org/10.4028/www.scientific.net/AMR.1043.784
[34] V. Veintemilla, “Procesos de Moldeado”, 2020. En línea https://es.scribd.com/document/392162516/Procesos-de-Moldeado
[35] TAPPI. “Technical Association of the Pulp and Paper Industry. Test Methods. 2000-2001. Norma Estandarizadas”, 2001.
[36] Y. Zhang, C. Duan, S. Bokka,, Z. He y Y. Ni, “Molded fiber and pulp products as green and sustainable alternatives to plastics” A mini review, 2021.
[37] C. Huang, L. Feng, Z. Zhang, S. Yang y J. Li,“Improvement of molding process of pulp molding products based on experimental study and simulation analysis”. The International Journal of Advanced Manufacturing Technology, 116, 3425–3435, 2021. En línea https://doi.org/10.1007/s00170-020-06472-0
[38] L. Jaramillo y A. Cuartas,“Elaboración de materiales compuestos a partir de cascarilla de arroz y matrices termoplásticas”. Tecnológico de Antioquía, 2020. En línea https://dspace.tdea.edu.co/handle/tdea/928?locale-attribute=en
[39] M. Hubbe, R. Venditti y O. Rojas,“What happens to cellulose fibers during papermaking and recycling? A review”, BioResources, 2(4), 739-788, 2007.
[40] H. Jiang, H. Meng, H. Wang y Z. Wang,“Comprehensive utilization of tobacco industry waste:. A review”, Journal of cleaner production, 255, 120338, 2020.
[41] V. Kumar, S. Luthra y R. Gupta, “A Review on Tobacco as a Potential Source of Cellulose and its Applications. International”. Journal of Chemical Studies,, 7(4), 2862, 2019.
[42] IMAM, CONICET – UNaM. IMAM, 2020. En línea imam.conicet: https://imam.conicet.gov.ar/gobierno/
[43] K. Lindeberg, M. Ross y K. Butler,“Tobacco use and the heart. Cleveland Clinic” Journal of Medicine, 85(12), 924-930, 2018.
[44] M. Guidobaldi, “Estudio sobre la gestión de residuos de papel y cartón con la finalidad de su recuperación, a través del reciclado”, Tesis de grado, Universidad Nacional de Córdoba, 2012.
[45] M. Kumar, Y. Negi, N. Singh, B. Sarkar y R. Singh, “Production and characterization of unbleached pulp from agricultural residue wheat straw employing alkaline sulfur-free processes. Frontiers in Energy”, Research, 8, 637148, 2021. doi:doi.org/10.3389/fenrg.2020.637148
[46] X. Li. Y L. Liu,“The effect of headgroup charge density of cationic surfactants on the compatibility and wetting of oil-wet kaolinite”. Applied Clay Science, 22(3-4), 139-152, 2003, doi:https://doi.org
[47] Gobierno Nacional de Argentina, “Plan Argentina Innovadora”, Obtenido de Agroindustria, 2020. En línea https://www.argentina.gob.ar/ciencia/argentina-innovadora-2030/plan-argentina-innovadora-2020/agroindustria
[48] V. Kumar, V. Yadav y A. Singh,“Tobacco stem as an alternative raw material for paper industry”, Journal of Scientific and Industrial Research, 74(10), 527-530, 2015.
[49] R.Gupta, S. Luthra y V. Kumar, “Tobacco: Its Historical, Cultural, and Medicinal Importance with a Special Focus on its Usage in Paper Manufacture”. Indian Journal of Forensic Medicine & Toxicology, 14(2), 1072-1076, 2020.
[50] Mongabayauthor, “Cambio climático”, 2014. En línea https://es.mongabay.com/2014/04/como-la-agricultura-industrial-esta-contribuyendo-al-cambio-climatico/
[51] N. Aguilar, “El reciclado de papel y cartón”. Ciencia y Cultura; elementos, 2004.
[52] ASPAPEL, “Tu papel es Importante”. Madrid: Asociación Española de Fabricantes de Pasta, Papel y Cartón, 2005.
[53] M. Didone, F. Chenlo, G. Tosello, “A new ecodesign approach for packaging made of biodegradable materials”, Journal of Cleaner Production, 141, 1141-1151, 2017.
[54] D. Dai, X. Fan, Y. Wang, C. Zhang y H. Jian,“What factors drive the price volatility of recovered paper in China?” Business Management Dynamics, 6(7), 16-28, 2017.
[55] C. Dislaire, B. Seantier, M. Muzy y Y.Grohens, “Mechanical and hygroscopic properties of molded pulp products using different wood-based cellulose fibers”. Polymers, 2021. En línea 13. doi:doi:https://doi.org/10.3390/polym13193225
[56] G. Gavazzo, R. Lanouette y J. Valade, J.“Fabricación de productos en pulpa moldeada”. Ciadicyp, 2017.
[57] K. Caballero, W. Patiño, B. Alvarado, J. Parra y D. Rodriguez, “Obtención de acetato de celulosa a partir de papel reciclado: una alternativa para la producción de acetato de celulosa en Colombia”, 2020.
[58] O. Castellano, “Diseño de un sistema de recolección y disposición de papel como alternativa sustentable para “el consorcio el sitio” (municipio paz castillo, estado miranda). Universidad de Carabobo facultad ingeniería escuela de ingeniería civil departamento de ingeniería ambiental”,Trabajo Especial de Grado presentado como requisito para optar al título de Ingeniero Civil, 2011.